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Here are words similar to catch off-guard:
abash, abduction, absorb, absorb the attention, accept, acquire, acquisition, admiration, affright, alarm, allure, amaze, amazement, ambition, ambuscade, ambush, ambushment, anchor, appear unexpectedly, appreciate, apprehend, apprehension, arrest, arrestation, artful dodge, artifice, assail, assault, assimilate, astonish, astonishment, astound, astoundment, attack, attract, awe, awestrike, baffle, bag, bag of tricks, bait the hook, bamboozle, be brought down, be felled, be seized of, be struck down, be traumatized, be unexpected, be with one, become popular, bedaze, bedazzle, beguilement, bewilder, bewilderment, bewitch, biff, birdlime, blaze, blaze up, blemish, blind, blitz, block, blockade, blockbuster, blow, bluff, board, boast, bob up, boggle, bomb, bombshell, booby trap, booty, bosey, bottleneck, bounce, bound, boundary condition, bowl down, bowl over, box, break out, breathless wonder, buck, buckjump, bug, burn, burst into flame, bushwhack, canon, capriole, captivate, captive, capture, catch, catch at, catch cold, catch fire, catch flat-footed, catch napping, catch off side, catch off-guard, catch on, catch on fire, catch on to, catch out, catch red-handed, catch tripping, catch unawares, catch up, catch-22, catching, charm, check, chicane, chicanery, chouse, clasp, clause, clear, clip, clout, clutch, collapse, collar, collaring, combust, come at, come by, come down on, come down with, come from behind, come in for, come into, come unawares, come upon, come upon unexpectedly, come with child, comprehend, con, conceive, condition, confound, confuse, conquest, contract, coquette, cordon, corral, coup, cover, crack, crack down on, creep up on, crux, curb, curtain, curve, curve-ball, curvet, cut off, date, daze, dazzle, dearest wish, decoy, defect, defection, deficiency, deliver, derive, descend on, descend upon, descry, desideration, desideratum, design, desire, detect, determent, deterrent, device, diamond, difficulty, dig, digest, ding, dirty deal, dirty trick, disadvantage, discern, discomfit, disconcert, discover, dismay, disturb, dive, do the unexpected, dodge, donnee, drag down, dragnet, draw, drawback, drop, drop in on, dumbfound, dumbfounder, dumbfoundment, earn, earthshaker, embarrass, enchant, encounter, engage, engage the attention, engage the mind, engage the thoughts, engross, engross the mind, engross the thoughts, enmesh, ensnare, ensnarl, entangle, enter into possession, enthrall, entice, entoil, entrap, enweb, erupt, escalator clause, escape clause, escape hatch, espouse, espy, exercise, eye-opener, failing, failure, fall, fall on, fall upon, fascinate, fascination, fast deal, fasten upon, fastener, fastening, fathom, fault, faute, faze, feint, fetch, fever, ficelle, figure out, find, fine print, fix, flabbergast, flagrante delicto, flame, flash upon one, flaw, flimflam, flirt, floor, fluster, foible, follow, fool, forbidden fruit, forcible seizure, foul, frailty, fugato, fugue, gain, gambit, gang up on, gather, gem, get, get an earful, get hold of, get it, get the drift, get the idea, get the picture, gimmick, gin, given, glimmering goal, go at, go for, go into shock, godsend, golden vision, good thing, googly, grab, grab at, grabbing, grapple, grasp, grip, grounds, gull, hang-up, harry, harvest, haul, have, have at, have it taped, hazard, hear, hear of, hear tell of, hideout, hippety-hop, hit, hit like lightning, hitch, hoax, hocus-pocus, hold, hold spellbound, hold the interest, hole, honey, hoodwink, hook, hook in, hooker, hop, hope, hurdle, hypnotize, immerse, imperfection, inadequacy, incredulity, infirmity, intercept, inveigle, involve, involve the interest, jam, jewel, joker, jolt, juggle, jump, jump at, jump over, ken, kicker, kidnapping, kink, know, land, land on, lasso, lay at, lay for, lay hands on, lay into, lay wait for, leap, leap over, leapfrog, learn, lie in ambush, lie in wait, light into, lime, limiting condition, little problem, lodestone, lodge, lure, lurk, lurking hole, magnet, make, marvel, marveling, master, meet with, mesh, mesmerize, monopolize, moor, mug, nab, nabbing, nail, negotiate, net, nick, nonplus, noose, nose-dive, objection, obligation, obsess, obstacle, obstruction, obstructive, obtain, occupy, occupy the attention, OD, one small difficulty, overdose, overhaul, overhear, overjump, overleap, overskip, overtake, overwhelm, parachute, paralyze, parameter, pass, pearl, perceive, peripeteia, perplex, petrify, picking up, pin, pinch, pitch, pitch into, plop, ploy, plum, plummet, plump, plunge, plunk, pop up, pounce, pounce on, pounce upon, pound, power grab, prehend, prehension, preoccupy, prerequisite, pride, pride and joy, prize, problem, procure, provision, provisions, proviso, pull down, pull up short, put out, puzzlement, rattle, reach, read, realize, reap, requisite, restrain, retreat, revelation, rift, rock, rondeau, rondino, rondo, rondoletto, root, rope, round, round up, roundelay, rub, run a temperature, running in, ruse, sack, sail into, saving clause, savvy, scheme, score, scramble for, scurvy trick, secure, seduce, see, see through, seize, seize on, seize the meaning, seizure, seizure of power, sense, sense of mystery, sense of wonder, set on, set upon, shadowing, shift, shock, shocker, shortcoming, sicken, sine qua non, ski jump, skin-dive, skip, sky-dive, sleight, sleight of hand, sleight-of-hand trick, slosh, small print, smite, snag, snap at, snare, snarl, snatch, snatch at, snatching, sneak attack, sniggle, sock, something missing, sound, spear, specification, spellbind, spot, spread the toils, spring, spring a surprise, spring upon, stagger, staggerer, stalking-horse, start, start aside, start up, startle, startler, steady, steeplechase, stick, stick fast, stipulation, stoop, stop, stratagem, strike, strike dead, strike dumb, strike root, strike with wonder, string, stumbling block, stumbling stone, stump, stun, stupefaction, stupefy, subterfuge, succeed, superfetate, surprisal, surprise, surprise attack, surprise ending, surprise package, surprise party, surveillance, swan, sweet patootie, sweetheart, sweetie, switch, swoop, swoop down, swoop down on, swoop down upon, taint, take, take a header, take aback, take by surprise, take captive, take hold, take hold of, take ill, take in, take prisoner, take root, take short, take the offensive, take unawares, take up, taking in, taking into custody, tangle, tangle up with, temptation, terms, thunderbolt, thunderclap, trap, treasure, trick, trip, troll, trophy, trouvaille, turn up, twig, ultimatum, understand, updive, upleap, upspring, vamp, vampire, vault, vulnerable place, wade into, waylay, weak link, weak point, weakness, wed, whack, whereas, wile, win, wind, windfall, winner, wonder,